Each individual molecule did reach an excited state and entered the air, as the air molecules themselves are already highly excited. Also, if the air already has enough moisture then the moisture molecules in the air can accumulate on surfaces that are cold enough that they lose their excited state energy, and a puddle could remain even in warm temperatures because as water leaves the puddle more can also accumulate there.
Thermodynamics is to engineers and physicists what ochem is to biologists and chemists. It’s the class you hope to leave with your sanity and gpa intact
Yup, I live in a desert climate and only clean up big puddles. Anything that doesn't make a splash when I step on it will be gone in under an hour, probably closer to 15 min.
My chemistry teacher once explained it to me like below. Does anyone know how much truth there is to this explanation?
Temperature as measured by a thermometer or your finger is an average. Not every single molecule has the same temperature. The molecules constantly bounce around, smashing into each other, transferring heat to each other. By chance, some molecules will get hit in just the right way by other molecules to reach a very high temperature and then it evaporates. So there is constantly a gradient of temperatures among the molecules and the ones with the highest temperature are the ones evaporating, until there is no liquid left at all.
As the average temperature increases, the chance of some molecules reaching a high enough temperature also increases, so warm water evaporates faster than cold water.
This also explains why evaporation cools down (like when you sweat): the molecules with the highest temperature are the ones evaporating, so the average temperature decreases as those high-temperature molecules leave the system. Only the relatively colder molecules are left behind - thus it cools as a whole.
I think it's much easier and truthful to stop talking about temperature and introduce speed in that context.
The average speed is what we percieve as temperature, but single molecules can be fast, so fast as to break the boundaries of the liquid pool and shoot up toward space.
But temperature is not just the speed of a molecule right? Isn't it also like the "energy" stored in the molecule, or its "wiggling" or something? Like a molecule moving very fast through space can still be at a very low temperature, right?
There's a bit more to it, but it's because of this effect.
There is actually a balance between liquid and gas state, just overwhelmingly in favor of liquid when at normal temperatures. There is a ratio of molecules that will hit each other and transition to gas, and an equal amount gas hitting liquid and condensing. At least when there is a balance between the two sides, aka 100% moisture in the air. Which is not how it is most places.
Normally there is always evaporated water in the air, and anything that evaporated will be moved away in any mildy ventilated area, as you say, it leaves the system. So it never reaches a balance, which is why things dry up at lower temps as water will always evaporate and leave the system.
This also explains why evaporation cools down (like when you sweat): the molecules with the highest temperature are the ones evaporating, so the average temperature decreases as those high-temperature molecules leave the system. Only the relatively colder molecules are left behind - thus it cools as a whole.
The main principle at work here is the enthalpy of vaporization. When matter changes state, there is an associated amount of energy that is absorbed or released - in the case of vaporization, energy must be absorbed. So when sweat forms on your skin and evaporates, it absorbs heat energy from your body in order to undergo that state change.
For water, the energy involved here is remarkably high, much higher than the energy stored by a few degrees difference in temperature. For example, if you wanted to boil off 1kg of water, it would take about 300 kJ to bring the temperature up to boiling from room temperature and over 2000 kJ to boil it all into steam.
The reason being that at any temperature where a liquid can be a gas (over zero degrees Celsius at standard pressure) some of that liquid will become gas.
And the reason for that is because the concept of temperature doesn't really work when you're talking about individual molecules. The average temperature might be 10° C but an individual molecule may very well get up to evaporation temperature, of course at that scale it doesn't really do anything other than disassociate itself from its neighbors.
Jokes aside, the boiling point exists because as the temperature of the water increases, so does its vapor pressure. At the boiling point, the vapor pressure becomes equal to the atmospheric pressure (1 standard atmosphere, or 760 torr). This is the reason why water boils at lower temperatures at higher altitudes!
He rather questions modus ponens? Things can have many causes, that is why the presence of the effect in absence of the cause does not mean there isn't a causal effect. Rain makes grass wet, even if the grass is wet without it having rained first, because there are presumably many reasons the grass can be wet (eg sprinklers), even if they are unknown to us. That having been said, this specimen is a hilarious face palm, all the same.