Low temperatures are associated with lower barometric pressure. Temperature and air pressure are proportional. You might be confusing density with air pressure?
The way it is taught in many Earth Science text books, is that if you have two similar volumes of air, but the first is colder than the second, the first will have a higher density, and therefore a larger mass, and therefore a higher air pressure (e.g. at the surface).
Following this logic, you expect higher pressure in colder areas, as long as the volume of air (the height of the air column) is the same. I think the answer to my question has to do with the latter: the atmosphere is less thick at the poles. As a result, despite the much lower temperatures, the air pressure at the poles is generally lower than (for example) at the subtropical highs.
the complication is that in meteorology, the volume of gas does not remain the same! if you're changing the mass, temperature, density, and pressure of a parcel of air, you definitely can't assume that the volume is constant
it's good to use a different ideal gas equation, instead of PV = nRT
(pressure x volume = n * R * Temperature)
we meteorologists tend to stick to unit masses, and use:
Pressure = density ×R×T, instead
i.e. when temperature decreases, pressure decreases