![chemistry](https://mander.xyz/pictrs/image/197c7fb5-7300-46cf-ab7b-25a2f4085a5f.png?format=webp&thumbnail=48)
Chemistry
- Making Copper Parts from Algaecide | HyperspacePirate
YouTube Video
Click to view this content.
- [NurdRage] Extracting Thorium Dioxide from Thoriated Tungsten Rods
YouTube Video
Click to view this content.
New NurdRage video!
Nice to see another amateur-accessible source of thorium, since incandescent gas mantles have mostly switched to yttrium.
I wonder what the easiest way would be to reduce the thorium dioxide to thorium metal?
- [Hyperspace Pirate] Making Liquid Nitrogen with my Homemade Cryocooler
YouTube Video
Click to view this content.
Making liquid nitrogen is quite an achievement, especially using salvaged air conditioner and refrigerator parts. A nice application of the Joule-Thomson effect and countercurrent exchange too.
- [NurdRage] Make Nitric Acid without Sulfuric Acid by Oxalate Precipitation
YouTube Video
Click to view this content.
Another useful example of producing a strong acid from a weak acid by using precipitation as the driving force.
- Electrochromic windows with fast response and wide dynamic range for visible-light modulation without traditional electrodes - Nature Communicationswww.nature.com Electrochromic windows with fast response and wide dynamic range for visible-light modulation without traditional electrodes - Nature Communications
Cheng Yang and co-workers develop an “electrode-free” electrochromic window, featuring a simplified fabrication process and delivering superior optical modulation capability.
- [Cody'sLab] Can I Use Thermite to Cast an Iron Pan?
YouTube Video
Click to view this content.
Cody plays with thermite... again.
- [NurdRage] Extracting Radioactive Salt from Chornobyl Blueberries
YouTube Video
Click to view this content.
cross-posted from: https://sh.itjust.works/post/21614029
> One of the OG YouTube chemists dabbles in some radiochemistry and spectroscopy.
- [NurdRage] Make sulfuric acid from oxalic acid with the sun
YouTube Video
Click to view this content.
Not very practical, but the chemistry is interesting. Producing a strong acid from a weak acid by using precipitation as the driving force is something I don't see very often.
- [NurdRage] Measuring Density with Pycnometers, Hydrometers, and Graduated Cylinders
YouTube Video
Click to view this content.
A bit of analytical chemistry for a change. I had never heard of a pycnometer!
- [NurdRage] Make Potassium Nitrate and Sodium Nitrate from Calcium Nitrate - An Alternative to Ammonium Nitrate
YouTube Video
Click to view this content.
Very useful video. Nitrate salts are a foundational feedstock in amateur (and professional) chemistry.
Edit: NurdRage reuploaded a slightly censored version: https://www.youtube.com/watch?v=RlonW4iJYrw
- NurdRage Oleum Synthesis Videos
NurdRage has published a couple videos on oleum synthesis:
- Lab Notes - Making Oleum - Successful - (April 21-2024)
- Lab notes - Making Oleum - 20% yield improvement - (May 4th - 2024)
Still optimizations to be done, but cool work so far. I love that one of the OG chemistry YouTubers is still doing interesting work.
- Thalidomide - Periodic Table of Videos
YouTube Video
Click to view this content.
A long-time viewer of Periodic Videos grew up to study chemistry, and invented a new synthetic route for thalidomide.
Also, TIL that thalidomide still has several medical uses, as long as the recipients are not pregnant.
- [Periodic Videos] Tungsten (new) - Periodic Table of Videos
YouTube Video
Click to view this content.
- Boffins deem Google DeepMind's material discoveries rather shallowwww.theregister.com Boffins deem Google DeepMind's material discoveries shallow
Web titan rejects criticisms, insists AI-found compounds are legit
- [NurdRage] Purification of Sulfuric Acid by Distillation - Revisited
YouTube Video
Click to view this content.
- [Extractions&Ire] Making Bismuth Germanate in the microwave
YouTube Video
Click to view this content.
- Cage escape governs photoredox reaction rates and quantum yields - Nature Chemistrywww.nature.com Cage escape governs photoredox reaction rates and quantum yields - Nature Chemistry
The spontaneous recombination of photogenerated radicals surrounded by solvent molecules is an important energy-wasting elementary step in photoredox reactions. Now the decisive role that cage escape plays in these reactions is shown in three benchmark photocatalytic reactions, with quantitative cor...
- Electric vehicle battery chemistry affects supply chain disruption vulnerabilities - Nature Communicationswww.nature.com Electric vehicle battery chemistry affects supply chain disruption vulnerabilities - Nature Communications
Electric vehicle battery supply chains are currently vulnerable to supply disruptions in China, but research shows that the cumulative effect of multiple supply chain steps creates additional vulnerabilities across multiple critical battery minerals.
- The anti-aromatic dianion and aromatic tetraanion of [18]annulene - Nature Chemistrywww.nature.com The anti-aromatic dianion and aromatic tetraanion of [18]annulene - Nature Chemistry
A previous investigation of the anti-aromatic dianion of [18]annulene concluded that it consists of a mixture of two isomers. Now it has been shown that this dianion exists as a single isomer, with a different geometry from neutral [18]annulene, and that it can be reduced further to an aromatic tetr...
- A programmable hybrid digital chemical information processor based on the Belousov-Zhabotinsky reaction - Nature Communicationswww.nature.com A programmable hybrid digital chemical information processor based on the Belousov-Zhabotinsky reaction - Nature Communications
Computing platforms based on chemical processes can be an alternative to digital computers in some scenarios but have limited programmability. Here the authors demonstrate a hybrid computing platform combining digital electronics and an oscillatory chemical reaction and demonstrate its computational...
- [Hyperspace Pirate] Automated Ethylene Production Plant
YouTube Video
Click to view this content.
- Burning 50lbs of Thermite Made From 400 Soda Cans
YouTube Video
Click to view this content.
Cody Reeder makes thermite and has a nice "campfire".
- Dishwasher guide: salt will harm the stainless steel lining. What about salt water in stainless steel pots?
The manual for my dishwasher says to refill salt just before running a wash cycle, because if any grains of salt spill onto the stainless steel interior it will corrode. If it runs right away, no issue because the salt is quickly dissolved, diluted, and flushed.
So then I realized when I cook pasta I heavily salt the water (following the advice that pasta water should taste as salty as the ocean). But what happens when I leave that highly salty brine in a pot, sometimes for a couple days to reuse it? Does that risk corroding the pots?
- Compound Interest: Women in Chemistrywww.compoundchem.com Compound Interest: Women in Chemistry
Explorations of everyday chemical compounds
- Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene - Nature Chemistrywww.nature.com Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene - Nature Chemistry
Switching the magnetic state of a polycyclic conjugated hydrocarbon in a reversible and controlled manner is challenging. Now, by means of single-molecule scanning probe microscopy, an indenofluorene isomer on ultrathin NaCl films has been shown to adopt both open- and closed-shell states. Furthermo...
- DeepMind's robot chef cooks up 'novel' materials with a side of controversy – Chemists dispute research claiming millions of recipes for inorganic crystalline compoundswww.theregister.com 'Novel' AI-made materials not actually new – study
Published report 'should be retracted as the main claim of discovery is wrong', UCL chemistry professor tells us
- The World’s Strongest Acid Might be Gentle Enough to Eat
YouTube Video
Click to view this content.
If you don't want to watch the entire video, it's a Carborane acid.
I'd love to see what the molecular orbitals look like. It's not every day that you see carbon forming six "bonds".
- Helium is an essential material for research and medical equipment, but it’s nonrenewable and difficult to recycletheconversation.com Helium is an essential material for research and medical equipment, but it’s nonrenewable and difficult to recycle
With the fourth significant shortage of helium in a decade continuing, companies and researchers are looking for alternative sources.
- Is sulfuric acid good for cleaning a boiler heat exchanger? What about ultrasonic baths?
cross-posted from: https://lemmy.dbzer0.com/post/12359577
> There are a few youtube videos where someone suggests using sulfuric acid to clean a secondary plate-style heat exchanger (for example). Yet I’ve heard sulfuric acid is extremely corrosive to metal, so something seems off about that advice. I certainly would not want an internal leak to cause radiator fluid to enter the tap water. I saw a drop of sulfuric acid land on a galvanized steel pipe once and within minutes it was rusted on the spot. > > This guy also says sulfuric acid is an option but also says there is a safer alternative acid -- yet he did not mention what it is! Does anyone know? > > This guy says he uses an ultrasonic bath but he does not say what chemicals he uses. Would distilled white vinegar be good for this? > > Note these questions are very loosely related to this thread which describes a problem I am having, but really it’s a separate discussion. Secondary exchangers need periodic maintenance regardless of whether this is my current problem. I saved my previously clogged heat exchanger from a few years ago so I could work on cleaning it. I have a quite small ultrasonic I could try, but I cannot submerge the whole exchanger. I would have to stand it on end and only clean a few centimeters deep.
- Dehumidifying long-term harms masonry?
cross-posted from: https://lemmy.dbzer0.com/post/10839711
> A top-floor room that’s not currently used has mold from excessive dampness. For a month I have been running a dehumidifier as it’s too cold to open the window. > > Is this a good idea? > > My concern: I heard about running a dehumidifier long-term in a damp basement is a bad idea because making the air more dry than the wall causes moisture to continuously flow from the outside in. That flow supposedly has the effect of washing the masonry through the capillaries and causing it to break down and weaken. In my case it’s not a basement, but similar because the exterior wall is non-stop wet from the frequent rains (possibly even leaky.. i think water seeps in). > > I have the humidity set to 55%. I wonder if there is an optimum setting that would inhibit mold without overly causing water to flow through the wall (which is very old brick+mortar and rendered over on both sides, no insulation). > > BTW, the water collected in the dehumidifier looks clean. Is it good for drinking?
- How To Clean Chemistry Glasswarewww.chem.rochester.edu How To
Demystifying Synthetic Organic Chemistry since 2004. Laboratory Techniques and Methods to Improve your Experimental Skills.
- Chemists create organic molecules in a rainbow of colors that could be useful as organic light-emitting diodesphys.org Chemists create organic molecules in a rainbow of colors that could be useful as organic light-emitting diodes
Chains of fused carbon-containing rings have unique optoelectronic properties that make them useful as semiconductors. These chains, known as acenes, can also be tuned to emit different colors of light, which makes them good candidates for use in organic light-emitting diodes.
- Zapping manure with special electrode promises an efficient method to produce fertilizers, other chemicalsnews.wisc.edu Zapping manure with special electrode promises an efficient method to produce fertilizers, other chemicals
The researchers' preliminary analyses show it could offer considerable benefits by cutting water and air pollution while simultaneously creating products that farmers could use or sell.
- Ultrasonic manual advises not to use ammonia and to use /cold/ water
The manual for an ultrasonic cleaner says:
> * “Cold, clean tap water is generally best suited as cleaning fluid. The cleaning effect can be enhanced by the addition of approximately 3 drops of washing-up liquid. Do not use caustic cleaners, ammonia, bleach or heavily perfumed detergents.” (emphasis mine)
I know a professional jeweler with decades experience who cleans jewelry (mostly gold) using “Mr. Clean”¹ and ammonia, diluted, in an ultrasonic tub. The cheap ultrasonic I bought for myself is not for pros - but jewelry cleaning is the advertised purpose and it has a stainless steel tub just like the pro models have.
So the question is, what’s the purpose of the ammonia avoidance guidance, and is the pro jeweler I know making a mistake by using ammonia?
UPDATE: I also have to question why the manual says to use cold water. Pro ultrasonics have built-in heating elements. The pro jeweler waits until the solution is hot before using it.
footnote:
① out of curiosity, is there a brand-neutral name for “Mr. Clean” (aka “Mr. Propre” in French regions)?