Irony of Brave Browser
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Advertisement directly injected into the video stream (such as Twitch/Netflix) can be harder to block for any current adblockers
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I'm hopeful something like Sponsorblock will show up for (twitch and others) and save the day
TTV-LOL Pro takes care of almost all Twitch ads
Didn't had any issue with it so far. Not sure what you're facing though. It just has some basic setup (nothing complicated). Maybe look to one of the step-by-step guide on the internet to find out where things are going wrong?